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Author: Carmen Ocal

SPM platform @InCAEM: In Situ Correlative Facility for Advanced Energy Materials (PRTR-C17.I1)

Scanning Probe Microscopy Platform within the InCAEM project 

InCAEM is part of the Planes Complementarios programme, launched and funded by the Ministry of Science and Innovation together with the Generalitat de Catalunya, with the support of NextGeneration EU funds. InCAEM is led by ALBA and belongs to the Advanced Materials project, aimed at developing new sustainable materials to be used in batteries, electric vehicles or solar cells, among others.

The SPM platform will count with diverse SPMs within the ALBA synchrotron installations to provide the local probe characterization in correlative experiments with ALBA beamlines.
ICMAB is responsible of two laboratories housing three SPMs: STM/ncAFM under UHV (SPECS) and two FX40 (Park Systems) working in different environments from gas to liquids, one installed inside a Glovebox (MBraun).

Full updated information of the joint project can be found in the section “InCAEM” of the ALBA instrumentation website.

OPINOS: Operando and in-situ multimode characterization of organic semiconductors for a comprehensive design of high performance electronic devices (PID2022-136802NB-I00)

Operando and in-situ multimode characterization of organic semiconductors for a comprehensive design of high performance electronic devices (OPINOS)

The exceptional chemical versatility of pi-conjugated organic materials as organic semiconductors
(OSCs), coupled with their ease in processing and adaptability to any substrate shape, size, and
type, make them excellent candidates for a broad range of (opto)electronic applications addressing
the fields of energy, environment, health, information, communication, robotics, and sensing. And
still, in spite of the great progress over the last few years, organic light emitting diodes (OLED)
are the only organic devices commercialized so far. One of the solid-state devices that has been at
the heart of the quest for commercially viable organic electronics is the organic field-effect
transistor (OFET), not only as electronic component in circuits, but also for the development of low cost
(bio)-chemical sensors. Furthermore, co-crystallization of molecules with electron donor (D) and
acceptor (A) properties to form charge-transfer complexes (CTCs) have emerged as one of the promising
field of research to obtain novel electrical and optical properties, which are far beyond the
performance of single materials, and avoiding complicated and time-consuming organic synthesis
procedures. Selection of suitable D and A systems enables a large range of tunable structures, i.e.,
offering a library of high-performance organic semiconductors with a fascinating prospect of
applications. While the parent compounds tend to be unipolar semiconductors, CTCs can vary in band
gap from insulators to metals, and can even be superconductors. In relation to OFETs, organic
CTCs provide a new way to realize OSC semiconductors with ambipolar behavior and air-stable n-type
OFETs and near-infrared photo-response. However, several challenges remain before OFETs-related
applications can become a widespread commercial reality. Despite its accepted importance by the
organic electronics community, optimizing the performance of OSCs through thin film engineering is
complicated by the fact that the relationship between microstructure, morphology, and transport
properties is still far from being well established. Besides, polymorphism can add a major hurdle to
overcome for a promising functional property to be exploited.

Efficient Fullerene-Free organic solar cells MSCA Doctoral Network

The EIFFEL project responds to the urgent need for advancements in NFA materials and NFA-based OSCs, as highlighted by the REPowerEU initiative. While Europe has lost leadership in device performance to Asia, particularly in NFAs, EIFFEL aims to be a game-changer by employing goal-driven design strategies and collaborating with stakeholders. 

EIFFEL is structured in 6 work-packages (WPs): three are dedicated to research activities, including 10 individual projects, and the remaining three are related to training (WP 2), dissemination (WP 6) and management (WP 1)

Full information about the EIFFEL network and the consortium will be available and updated in the EIFFEL website and social media platforms:

Facebook: https://www.facebook.com/eiffel.doctoral.network

LinkedIn: https://www.linkedin.com/company/eiffel-dn

Twitter: https://twitter.com/EiffelDN

2024

Polar polymorphism: a new intermediate structure towards the thin-film phase in asymmetric benzothieno[3,2-b][1]-benzothiophene Derivatives
S. Yan, D. Cornil, J. Cornil, D. Beljonne, R. Palacios-Rivera, C. Ocal, E. Barrena
Chem. Mater. 2024, 36, 1, 585–595  DOI: 10.1021/acs.chemmater.3c02926

Monodentate versus Bidentate Anchoring Groups in Self-Assembling Molecules (SAMs) for Robust p−i−n Perovskite SolarCells
E. Yalcin, E. Aktas, M. Mendéz, E. Arkan, J. G. Sánchez, E. Martínez-Ferrero, F. Silvestri, E. Barrena, M. Can,* S. Demic,* E. Palomares*
ACS Appl. Mater. Interfaces, 2023, 15, 49, 57153–57164 DOI: 10.1021/acsami.3c13727

Compelling DNA Intercalation through “Anion-Anion” Anti-Coulombic Interaction: Boron Nanocarriers as Promising Anticancer Agents
L. Gutiérrez-Gálvez, T. García-Mendiola, E. Lorenzo, M. Nuez, C. Ocal, S. Yan, F. Teixidor, T. Pinheiro, F. Marques, C. Viñas
Journal of Materials Chemistry B, 2024, 12, 9550-9565 DOI: 10.1039/D4TB01177E  (Supporting Information)

This article was selected by the Editors to be this issue Journal Cover.

Imaging the adsorption sites of organic molecules on metallic surfaces by an adaptive tunnelling current feedback
D. Martin-Jimenez, Q. Zhong, A. Schirmeisen, D. Ebeling
Nanotechnology,  2024, 35, 47, 475703 DOI 10.1088/1361-6528/ad726a 

KCN Chemical Etching of van der Waals Sb2Se3 Thin Films Synthesized at Low Temperature Leads to Inverted Surface Polarity and Improved Solar Cell Efficiency
M. Jiménez-Guerra, L. Calvo-Barrio, J. M. Asensi, I. Caño-Prades, S. Yan, E. Barrena, J. Puigdollers, Z. Jehl, Y. Sánchez, E. Saucedo
ACS Appl. Energy Mater. 2024, 7, 3, 874–884  DOI: 10.1021/acsaem.3c01584

Collaboration with BCT-UAB

Taking advantage of their proximity, members of the PSCI group at ICMAB-CSIC actively collaborate with the Science and Technology Library (BCT) of the Universitat Autònoma de Barcelona (UAB).

 Presentació: Els Premis de Física Real Sociedad Española de Física-Fundación BBVA 2024 al campus de la UAB 
Daniel Martín-Jiménez 
November 26, 2024  

The winners of the 2024 RSEF-BBVA Awards, Daniel Martín Jiménez (postdoctoral researcher at ICMAB-CSIC) and Martí Perarnau Llobet (Ramón y Cajal postdoctoral researcher at the Department of Physics, UAB), both working on the Bellaterra campus, presented to the audience the research projects for which they were honored. The event was organized by the Science and Technology Library and was preceded by a presentation featuring Ignasi Fina Martínez (tenured scientist at the Institute of Materials Science of Barcelona, ICMAB-CSIC).

The event was recorded and is available at the following link: https://www.youtube.com/watch?v=PbCo8M0Q8Xw

POETIC SLAM: #CiènciaiPoesia
Daniel Martín-Jiménez 
September 26, 2023

A Poetry Slam on Science took place in the library of Science and Technology of the UAB with the participation of Daniel Martín Jiménez from the PCSI group of ICMAB-CSIC with the poem Helio Líquido. Daniel’s scientific poem Helio líquido was first published on 11th December 2023.

We are partners of EIFFEL (Efficient Fullerene-Free organic solar cells) an HORIZON MSCA-Doctoral Network

Our group participates in the recently approved EIFFEL project, one of the MSCA Doctoral Networks 2022 (HORIZON-MSCA-202-DN-01) within the HORIZON Europe Framework.

EIFFEL stands for EffIcient Fullerene-Free organic solar cELls.
The whole consortium will recruit, train and supervise 10 talented Early Stage Researchers (ESRs) to design and synthesize novel materials suitable for the next generation of efficient and stable Organic Photovoltaics (OPV). EIFFEL is thought as a training programme uniquely designed to provide the ESRs with multidisciplinary training interlinking chemistry, materials science, physics, computer science, and transferable skills. EIFFEL’s ambition is to form a new generation of creative, entrepreneurial and innovative young researchers with the organizational abilities needed to succeed in interdisciplinary high-tech sectors.
The project will start in early 2024.

Information and a summary about this network will be updated in the EIFFEL website and social media platforms:

Facebook: https://www.facebook.com/eiffel.doctoral.network

LinkedIn: https://www.linkedin.com/company/eiffel-dn

Twitter: https://twitter.com/EiffelDN

 

European Researchers’ Night, Science week, Science Fest and Pint of Science

The members of PSCI take part in annual activities that bring science closer to society. They have participated in the Barcelona Science Festival (Spring), the European Researchers’ Night (last weekend of September), and the Science Week. There, they run science workshops for children, storytelling sessions, and talks, with the support of the ICMAB-CSIC outreach team.

Science week in Barcelona
Anna Crespi and Daniel Martín-Jiménez
November 15, 2025  
As part of the LAB TOUR 2026 project, researchers from ICMAB-CSIC organized a new event during Science Week, where researchers Anna Crespi and Daniel Martín gave a talk on the pigments used in Romanesque art at Casa de Soria in Barcelona. The event gathered roughly 100 people, including members of the House and external public. The talk — blending history, society and science — used Romanesque pigments as a guiding thread to explore the connections between Soria and Barcelona.
 The European Researchers’ Night in Soria 
Stefania Sandoval, Judith Oró and Daniel Martín-Jiménez
September 26, 2025  
As part of the LAB TOUR project, researchers from ICMAB-CSIC travelled to Soria to celebrate, for the first time, the European Researchers’ Night in the city. At the ‘Casino Círculo Amistad Numancia’, they presented the LAB TOUR 2026 project, delivered a talk on nanotechnology, and offered workshops for children and young audiences on electricity and magnetism, light and optics, and optical and electronic microscopy.
Festa de la Ciència/ Science Fest in Barcelona
Daniel Martín-Jiménez
June 9, 2024  
Daniel Martín Jiménez took part in an event at El Born in Barcelona, where he performed a storytelling session about Fray Tomás and led hands-on activities exploring biological materials and their colours.
 The European Researchers’ Night in Barcelona 
Daniel Martín-Jiménez and Rosa L. Zaffino
September 29, 2023  
Daniel Martín Jiménez (PCSI group) and Rosa L. Zaffino (FunNanoSurf), both from ICMAB-CSIC, organized a scientific workshop at the Science Night of Catalonia at CosmoCaixa. They rescued from the past the historical character of Fray Tomás de Berlanga, a monk whose life was devoted to Christian faith and science. Children from 3 to 5 years learned about animals, fruits and colors as part of an educational and Nature care activity.
Pint of Science in Barcelona 
Ana Pérez and Esther Barrena
May 16, 2017  
On May 16th, PCSI members and ICMAB researchers Esther Barrena and Ana Pérez gave two talks at Michael Collins bar. Esther presented “Planilandia: un LEGO en dos dimensiones”, introducing graphene and other 2D materials. Ana delivered “Ver y tocar átomos y moléculas”, explaining how scanning microscopy allows us to visualize matter at the nanoscale.

CLOSED PhD position: Operando and In-situ Multimode Characterization of Organic Semiconductors

PhD position

Operando and In-situ Multimode Characterization of Organic Semiconductors for a Comprehensive Design of High-Performance Electronic Devices

Organic semiconductors have emerged as a breathtaking prospect, promising a new era of electronic devices with unparalleled versatility and eco-friendliness. Their applications span a wide spectrum, encompassing organic light-emitting diodes (OLEDs) that bring life to vivid displays, organic photovoltaics (OPVs) that harness the sun’s energy, and organic field-effect transistors (OFETs) that drive the future of flexible electronics. Yet, to truly unleash their full potential across these diverse fields, we must grasp the profound intricacies governing structural order and morphology in thin films and their impact on charge transport. In this PhD project, we aim at pushing the boundaries of knowledge by operando and in-situ characterization of organic semiconductors thin films. This research work combines advanced characterization methodologies techniques, including x-ray diffraction, Scanning Probe Force Microscopy, and electrical measurements, to study the dynamic changes in material properties occurring during growth or thermal annealing and to achieve a microscopic understanding. Furthermore, the work will address the use of multi-component thin films paving the way for applications in NIR photo-detection and photo-thermal conversion.

Qualifications and Requirements:

A strong academic background in materials science, physics, or a related field, a curious and analytical mindset, and the will to learn experimental research.

Benefits:

Our group, the Physical Chemistry of Surfaces and Interfaces (PCSI)), has strong expertise in x-ray scattering techniques using synchrotron radiation as well as in advanced scanning probe microscopy.  Taking advantage of the relevant role that the PCSI group plays in the SPM platform of the InCAEM project, the doctoral thesis will include the combination of state-of-the-art methodologies that provide an exceptional environment for cutting-edge research. We offer a team-oriented, motivating work atmosphere, which will allow the candidate to develop independence and soft and technical skills.

Materials Science Institute of Barcelona (ICMAB-CSIC)

The work will be carried out at the Materials Science Institute of Barcelona (ICMAB-CSIC), a research center located at the UAB campus (~35 min from downtown Barcelona by public transportation). (ICMAB-CSIC) is a Severo Ochoa Excellence center focusing on cutting-edge research in functional materials in the fields of electronics, energy, and nanomedicine. With over 250 members from 30+ nationalities, ICMAB-CSIC offers a highly international and dynamic environment for enthusiastic young researchers.

Application Process:

Interested candidates are invited to contact Esther Barrena (ebarrena@icmab.es) and Carmen Ocal (cocal@icmab.es) and submit a CV.

NOTE: Only preselected applications will get an answer and will obtain an appointment to carry out an interview.

The position is intended to start around October 2023, financed under the project PID2022-136802NB-I00.

Please note that the deadline indicated is an estimation, and the position will remain open until we find the right candidate.

CLOSED PhD position: Interface engineering for the next future well-performing organic devices

Interface engineering for the next future well-performing organic devices

When Herbert Kroemer (Nobel Prize in Physics, 2000) coined the famous phrase “the interface is the device”, he referred to the success of devices based on thin inorganic semiconductor films for photonic and electronic applications that started more than four decades ago.

This statement also holds for organic semiconductors, which are predestined by deposition on large-area and flexible substrates to be the electrically and optically active layers with important applications in electronics, lighting, photovoltaics and displays. A good number of interfaces (organic/organic and organic/inorganic) are inherent to all organic electronic devices and, because their relevant role in device performance, Kroemer’s phrase can be extended:

The interfaceS are the organic deviceS”.

With that certainty added to the experience and equipment of the Physical Chemistry of Surfaces and Interfaces (PCSI) group, we offer a doctoral position.

The doctoral project (*) aims to obtain structural control of organic semiconductors thin films for the near future manufacture of more reliable organic electronic devices. The proposal points to a detailed microscopic understanding of crystallography, polymorphism, role of interfaces, as well as to determine the conditions for a good thermal stability of thin films prepared by various physical and chemical methodologies. Furthermore, the use of multi-component thin films (e.g., donor/acceptor organics) and proper fabrication protocols will allow obtaining co-crystalline charge transfer complexes (CTC) thin films, paving the way for applications in NIR photo-detection and photo-thermal conversion.

Taking advantage of the relevant role that the PCSI group plays in the SPM platform of the InCAEM project, the doctoral thesis will include the combination of state-of-the-art methodologies for correlative and in-situ experiments. In particular, in-situ and real-time characterization during thin film growth and/or post-growth treatments (e. g., thermal and solvent annealing) using diverse modes of scanning probe microscopy, one of the most versatile characterization tools in nanoscience, combined with powerful X-ray synchrotron techniques.

Materials Science Institute of Barcelona (ICMAB-CSIC)

The PhD fellow will have the unique opportunity to carry out a doctorate in the scientific active and lively environment of ICMAB and the synchrotron ALBA, and acquire the knowledge to master state-of-the-art techniques for organic thin films growth and novel characterization instruments with the purpose of correlating structural details with device performances. The collaborative activity of the PCSI teams at international level (EU consortiums, training networks and bilateral collaborations) will pave the chance of the fellow towards an international career.

Application and requirements

Candidates with motivated attitude for experimental tasks and good academic background, must hold a Master’s degree in materials science, physics, nanoscience, nanotechnology or related fields at the moment of the formal application. 

We encourage interested candidates to send a CV and motivation letter to the following researchers:

Daniel Martín-Jiménez: dmartin@icmab.es
Esther Barrena: ebarrena@icmab.es
Carmen Ocal: cocal@icmab.es

NOTE: Only preselected applications will get an answer and will obtain an appointment to carry out an interview.

Please note that the deadline indicated is an estimation, and the position will remain open until we find the right candidate.

* The doctoral position will be financed under project PID2022-136802NB-I00